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Modulation Strategies of Cu-based Electrocatalysts for Enhancing Electrocatalytic CO2 Conversion

By (author) Lei Wang, By (author) Zhongchao Tan, By (author) Yimin Wu

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The electrocatalytic reduction of COâ‚‚ into high-value multi-carbon products represents a crucial pathway toward achieving carbon neutrality and sustainable chemical production. The transition from lab-scale studies to industrial-scale implementation is imperative to bridge the gap between fundamental mechanistic insights and practical applications. This book explores the mechanistic understanding and functional design of electrocatalysts for COâ‚‚ electroreduction, focusing on bridging the gap between lab-scale research and industrial-scale implementation. It systematically investigates the role of grain boundary structures, oxidation states, and interfacial microenvironments in stabilizing Cu-based catalysts, thereby enhancing the selective production of multi-carbon products. By integrating oxidation and alloying strategies, this work introduces new approaches to modulate copper oxidation states, leading to improved catalytic performance. Advanced characterization techniques, including in situ multimodal spectroscopy, provide insights into the electrochemical stability of CuÎ´âº species and their impact on reaction pathways. Beyond catalyst design, this book extends the discussion to COâ‚‚ electrolyzer configurations, emphasizing membrane electrode assemblies and gas diffusion electrode engineering for scalable applications. The introduction of functionalized carbon black to modulate the interfacial environment, effectively suppresses the hydrogen evolution reaction, stabilizing active CuÎ´âº species and promoting ethylene production with high Faradaic efficiency. By integrating fundamental insights with industrial feasibility, this book offers a comprehensive guide for researchers and engineers developing next-generation COâ‚‚ electrolysis technologies, contributing to carbon-neutral chemical manufacturing and sustainable energy solutions.

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The Ballerina and the Bull: Anarchist Utopias in the Age of Finance

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288 pages
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Our moment has seen the resurgence of an anarchist sensibility, from the uprisings in Seattle in 1999 to the Occupy movement of 2011.

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Fifteen Dogs

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A pack of dogs are granted the power of human thought - but what will it do to them? A surprising and insightful look at the beauty and perils of consciousness.

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The Memory Collectors: A Novel

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320 pages

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